Synthesis and characterization of a novel polymeric ultraviolet absorber and its properties

被引：2
|
作者：
Zhu, Jinli [1 ]
Gao, Pengfei [1 ]
Sun, Tongming [1 ]
Wang, Miao [1 ]
Tang, Yanfeng [1 ]
机构：
[1] Nantong Univ, Sch Chem & Chem Engn, Nantong 226019, Peoples R China
来源：
POLYMER BULLETIN | 2015年 / 72卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Polymeric ultraviolet absorber; Covering UV-A and UV-B ranges; 2,4-Dihydroxybenzophenone; Cinnamate; UV-ABSORBERS; PHOTOPROTECTION; STABILIZERS; DERIVATIVES; SUNSCREENS; PROTECTION;
D O I：
10.1007/s00289-015-1368-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel polymeric ultraviolet absorber (UVA) poly (HAB-co-AMC-co-AA) (PHHA) has been prepared by solution copolymerization from 2-hydroxy-4-acryloy benzophenone (HAB), p-acryloy-methyl cinnamate (AMC) and acrylic acid and analyzed using FT-IR, UV-Vis, H-1 NMR and GPC. The results revealed two PHHA absorption peaks in UV-A and UV-B. Polymerizable monomer HAB was synthesized by the reaction of 2,4-dihydroxybenzophenone (UV-0) and acryloyl chloride (AC). Another monomer, AMC, was prepared from p-hydroxy-methyl cinnamate and AC. The results showed that HAB and AMC have high UV-absorbing performance in UV-A and UV-B, respectively. The photoantioxidant ability tests indicated that PHHA is an effective polymeric UVA that covers UV-A and UV-B ranges, and a synergism between the two monomers was observed.
引用
收藏
页码：1753 / 1761
页数：9
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