Synthesis of a Range of Iodine(III) Compounds Directly from Iodoarenes

被引：44

作者：

Merritt, Eleanor A. ^{[1
]}

Olofsson, Berit ^{[1
]}

机构：

[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, S-10691 Stockholm, Sweden

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 20-21期

基金：

瑞典研究理事会;

关键词：

Hypervalent compounds; Alkynes; Iodine; Iodonium salts; Benziodoxolones; ONE-POT SYNTHESIS; TRIFLUOROMETHANESULFONIC ACID; ALKYNYLIODONIUM SALTS; DIARYLIODONIUM SALTS; DIRECT ALKYNYLATION; FACILE SYNTHESIS; IODONIUM SALTS; HYPERVALENT; REAGENT; TRIFLUOROMETHYLATION;

D O I：

10.1002/ejoc.201100360

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first direct synthesis of an alkynyl(phenyl) iodonium salt from iodobenzene and an unprotected alkyne is described. The synthesis of the corresponding alkenyl(phenyl) iodonium salt is achieved from the TMS-alkyne, simply by means of changing the solvent. The one-pot synthesis of 1-arylbenziodoxolones and other iodine(III) compounds from iodine(I) precursors is also presented.

引用

页码：3690 / 3694

页数：5

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