Enantioselective phenyl transfer to aldehydes using 1,1′-bi-2-naphthol-3,3′-dicarboxamide as chiral auxiliary

被引：36

作者：

Ito, K ^{[1
]}

Tomita, Y

Katsuki, T

机构：

[1] Fukuoka Univ Educ, Dept Chem, Fukuoka 8114192, Japan

[2] Kyushu Univ 33, Fac Sci, Grad Sch, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 36期

基金：

日本科学技术振兴机构;

关键词：

zinc; asymmetric catalysis; 1,1 '-bi-2-naphthol; aryl transfer reaction;

D O I：

10.1016/j.tetlet.2005.06.161

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N,N.N'.N'-Tetra-n-butyl-BINOL-3,3'-dicarboxamide 5d was found to promote phenyl transfer from ethylphenylzinc to both aromatic and aliphatic aldehydes with high enantioselectivity up to 96% ee in tert-butyl methyl ether. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：6083 / 6086

页数：4

共 42 条

[41] Enantioselective Oxidative Cross-Coupling Reaction of 3-Indolylmethyl C-H Bonds with 1,3-Dicarbonyls Using a Chiral Lewis Acid-Bonded Nucleophile to Control Stereochemistry
Guo, Chang
Song, Jin
Luo, Shi-Wei
Gong, Liu-Zhu
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (32) : 5558 - 5562
[42] Enantioconvergent Cu-Catalyzed Intramolecular C-C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold
Yoshinaga, Yukako
Yamamoto, Takeshi
Suginome, Michinori
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (43) : 18317 - 18323

← 1 2 3 4 5 →