Enantioselective phenyl transfer to aldehydes using 1,1′-bi-2-naphthol-3,3′-dicarboxamide as chiral auxiliary

被引：36
作者：
Ito, K [1 ]
Tomita, Y
Katsuki, T
机构：
[1] Fukuoka Univ Educ, Dept Chem, Fukuoka 8114192, Japan
[2] Kyushu Univ 33, Fac Sci, Grad Sch, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 36期
基金：
日本科学技术振兴机构;
关键词：
zinc; asymmetric catalysis; 1,1 '-bi-2-naphthol; aryl transfer reaction;
D O I：
10.1016/j.tetlet.2005.06.161
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N,N.N'.N'-Tetra-n-butyl-BINOL-3,3'-dicarboxamide 5d was found to promote phenyl transfer from ethylphenylzinc to both aromatic and aliphatic aldehydes with high enantioselectivity up to 96% ee in tert-butyl methyl ether. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6083 / 6086
页数：4
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