Low-temperature oxidation of sulfur dioxide by molecular oxygen in aqueous solutions of non-transition metals trifluoroacetates

被引：0

作者：

Vishnetskaya, M. V. ^{[1
]}

Murtazina, Yu. V. ^{[1
]}

Skrepleva, I. Yu. ^{[2
]}

Mel'nikov, M. Ya. ^{[2
]}

机构：

[1] Gubkin State Univ Oil & Gas, Moscow, Russia

[2] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 85卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

molecular oxygen; active state; Bronsted acidity; oxidation; alkali metal; trifluoroacetates; ALKANES; ACID;

D O I：

10.1134/S0036024411050311

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidation of SO(2) was shown to occur in aqueous solutions of Li, Na, and K trifluoroacetates at room temperature. Oxidative activity of the non-transition metal trifluoroacetates increases on decreasing pH of solution and at equal pH values, it follows the sequence: Li < Na < K.

引用

页码：777 / 779

页数：3

共 5 条

[1] Low-temperature oxidation of sulfur dioxide by molecular oxygen in aqueous solutions of non-transition metals trifluoroacetates
M. V. Vishnetskaya
Yu. V. Murtazina
I. Yu. Skrepleva
M. Ya. Mel’nikov
Russian Journal of Physical Chemistry A, 2011, 85
[2] Homogeneous Redox Catalysts Based on Heteropoly Acid Solutions VI: Development of a Process for Low-Temperature CO Oxidation with Oxygen
Yu. A. Rodikova
E. G. Zhizhina
Catalysis in Industry, 2025, 17 (1) : 21 - 30
[3] Formation of alkyl radicals that are relatively unreactive with each other and with oxygen, in the low-temperature liquid-phase oxidation of hexafluoropropylene by molecular oxygen
Shapovalov V.V.
Theoretical and Experimental Chemistry, 1998, 34 (4) : 227 - 228
[4] Low-Temperature Liquid-Phase Radiation-Induced Oxidation of Hexafluoropropylene with Molecular Oxygen: Effect of Reaction Conditions on the Structure of Perfluoropolyether Polyperoxide
V. V. Shapovalov
High Energy Chemistry, 2000, 34 : 412 - 413
[5] Low-temperature oxidation of guaiacol to maleic acid over TS-1 catalyst in alkaline aqueous H2O2 solutions
Su, Ji
Yang, Lisha
Liu, Reed Nicholas
Lin, Hongfei
CHINESE JOURNAL OF CATALYSIS, 2014, 35 (05) : 622 - 630

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