Modulation of liquid structure and controlling molecular diffusion using supramolecular constructs

被引:6
作者
Varshney, Rohit [1 ]
Agashe, Chinmayee [1 ]
Gill, Arshdeep Kaur [1 ]
Alam, Mujeeb [1 ]
Joseph, Roymon [2 ]
Patra, Debabrata [1 ]
机构
[1] Inst Nano Sci & Technol, Sect 81, Sahibzada Ajit Nagar 140306, Punjab, India
[2] Univ Calicut, Dept Chem, Calicut 673635, Kerala, India
关键词
CROSS-LINKING; MICROCAPSULES; NANOPARTICLES; FABRICATION; INTERFACES; RELEASE; ROUTE;
D O I
10.1039/d1cc04417f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The non-equilibrium liquid structure was achieved by interfacial jamming of pillar[5]arene carboxylic acid (P[5]AA) mediated by hydrogen bonding interactions. The assembly was reversibly modulated via jamming to unjamming transition thus dynamically shaping the liquid droplets. Interestingly, these supramolecular constructs showed pH-switchable gated diffusion of encapsulants, hence showcasing a next generation smart release system.
引用
收藏
页码:10604 / 10607
页数:4
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