A convenient method for the N-formylation of amines at room temperature using TiO2-P25 or sulfated titania

被引：73

作者：

Krishnakumar, B. ^{[1
]}

Swaminathan, M. ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2011年 / 334卷 / 1-2期

关键词：

Sulfated titania; TiO2-P25; Formic acid; N-Formylation; Reusability; SECONDARY-AMINES; DERIVATIVES; QUINOXALINE; CATALYSIS; GLYCOL;

D O I：

10.1016/j.molcata.2010.11.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Semiconductor catalyzed N-formylation of a variety of amines using formic acid as formylating agent has been investigated. Primary and secondary amines were found to react efficiently with formic acid in the presence of TiO2-P25 or sulfated titania giving N-formyl derivatives in high yields at room temperature. Sulfated titania is found to be more efficient and reusable than TiO2-P25 for N-formylation of amines. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：98 / 102

页数：5

共 25 条

[1]

[Anonymous], SYNTHESIS

[2] FORMYLATION OF AMINES WITH CHLORAL AND REDUCTION OF THE N-FORMYL DERIVATIVES WITH LITHIUM ALUMINUM HYDRIDE [J].

BLICKE, FF ;

LU, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (15) :3933-3934

[3] A very simple and highly efficient procedure for N-formylation of primary and secondary amines at room temperature under solvent-free conditions [J].

Brahmachari, Goutam ;

Laskar, Sujay .

TETRAHEDRON LETTERS, 2010, 51 (17) :2319-2322

[4] ALKALI-PROMOTED AIPO4 CATALYSIS .1. ACID-BASE AND OXIDIZING-REDUCING PROPERTIES [J].

CAMPELO, JM ;

GARCIA, A ;

GUTIERREZ, JM ;

LUNA, D ;

MARINAS, JM .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 95 (02) :544-550

[5] A new facile method for the synthesis of 1-arylimidazole-5-carboxylates [J].

Chen, BC ;

Bednarz, MS ;

Zhao, RL ;

Sundeen, JE ;

Chen, P ;

Shen, ZQ ;

Skoumbourdis, AP ;

Barrish, JC .

TETRAHEDRON LETTERS, 2000, 41 (29) :5453-5456

[6]

CHEN FMF, 1979, SYNTHESIS-STUTTGART, P709

[7] Multi-component syntheses of heterocycles by transition-metal catalysis [J].

D'Souza, Daniel M. ;

Mueller, Thomas J. J. .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (07) :1095-1108

[8] A remarkably simple N-formylation of anilines using polyethylene glycol [J].

Das, Biswanath ;

Krishnaiah, Maddeboina ;

Balasubramanyam, P. ;

Veeranjaneyulu, Boyapati ;

Kumar, D. Nandan .

TETRAHEDRON LETTERS, 2008, 49 (14) :2225-2227

[9] VILSMEIER FORMYLATION AND GLYOXYLATION REACTIONS OF NUCLEOPHILIC AROMATIC-COMPOUNDS USING PYROPHOSPHORYL CHLORIDE [J].

DOWNIE, IM ;

EARLE, MJ ;

HEANEY, H ;

SHUHAIBAR, KF .

TETRAHEDRON, 1993, 49 (19) :4015-4034

[10] Wells-Dawson type heteropolyacid catalyzed synthesis of quinoxaline derivatives at room temperature [J].

Heravi, Majid M. ;

Bakhtiari, Khadijeh ;

Bamoharram, Fatemeh F. ;

Tehrani, Maryam H. .

MONATSHEFTE FUR CHEMIE, 2007, 138 (05) :465-467

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