Catalytic properties of the Ru promoted Co/SBA-15 catalysts for Fischer-Tropsch synthesis

被引：40
作者：
Cai, Qjn [1 ]
Li, Jinlin [1 ]
机构：
[1] S Cent Univ Natl, Coll Chem & Mat Sci, State Ethn Affairs Commiss & Minist Educ, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Fischer-Tropsch synthesis; Ru; promoter; Co/SBA-15;
D O I：
10.1016/j.catcom.2008.03.035
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ru promoted Co/SBA-15 catalysts were prepared by incipient wetness impregnation and characterized by XRD, H-2-TPR, H-2-TPD, O-2 titration and DRIFTS. The catalytic activity of the catalyst for Fischer-Tropsch synthesis was investigated in a fixed bed reactor (FBR). Their reducibility, CO adsorption capacity, Fischer-Tropsch synthesis activity and C5+ hydrocarbon selectivity increased with increasing Ru loading. The increases in activity and selectivity were attributable to the increased number of active sites as a result of the higher reducibility as well as the synergetic effect of Ru and Co. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：2003 / 2006
页数：4
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