Insertion Reactions of Diazomethanes and Electrophilic Boranes

被引：25
作者：
Neu, Rebecca C. [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
SITE OLEFIN POLYMERIZATION; BIFUNCTIONAL PERFLUOROARYL BORANES; FRUSTRATED LEWIS PAIRS; ORGANOBORON POLYMERS; BINUCLEAR CATALYSTS; ACID CATALYSTS; BORON; REACTIVITY; CHEMISTRY; 1,1-CARBOBORATION;
D O I：
10.1021/om2011613
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electrophilic pentafluoroarylboranes B-(C6F5)(3), PhB(C6F5)(2), and ClB(C6F5)(2) react with (trimethylsilyl) diazomethane, diphenyldiazomethane, or (pentafluorophenyl)diazomethane, affording insertion into the one or two B-C bonds in a facile and high-yielding route to the boranes (Me3SiCH(C6F5))B(C6F5)(2), (Me3SiCH-(C6F5))(2)B(C6F5), (Me3SiCH(C6F5))(Me3SiCH(Ph))B-(C6F5), (C6F5)ClB(CPh2(C6F5)), and (C6F5)(2)B(CH(C6F5)(2)).
引用
收藏
页码：46 / 49
页数：4
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