Dynamic mechanical behavior of flexible graphite made from exfoliated graphite

被引:32
作者
Chen, Po-Hsiu [1 ]
Chung, D. D. L. [1 ]
机构
[1] SUNY Buffalo, Composite Mat Res Lab, Buffalo, NY 14260 USA
关键词
SENSITIZED SOLAR-CELLS; ELECTRICAL-RESISTANCE; COUNTER ELECTRODE; FUEL-CELLS; PLATE; ANODE;
D O I
10.1016/j.carbon.2011.08.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The low-frequency dynamic mechanical properties of low density flexible graphite (0.027-0.089 g/cm(3), obtained by compressing exfoliated graphite at 0.3-1.7 MPa without a binder) are different in flexure and compression. The storage and loss moduli and the loss tangent are higher under flexure than compression. Under flexure, the storage modulus is essentially unaffected by increasing the static strain while the loss tangent and loss modulus decrease. Under compression, both storage and loss moduli increase with increasing static strain, while the loss tangent slightly decreases. The storage and loss moduli are higher and the loss tangent is lower for out-of-plane compression than for in-plane compression. The storage and loss moduli increase with increasing fabrication pressure, while the loss tangent decreases. Energy dissipation is much more effective under flexure than compression. Flexure appears to provide more sliding of the graphite layers than compression. For the highest energy dissipation under flexure, a low static strain is recommended; for high energy dissipation under compression, a high static strain is recommended. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:283 / 289
页数:7
相关论文
共 28 条
[1]   Modelling of exfoliated graphite [J].
Celzard, A ;
Marêché, JF ;
Furdin, G .
PROGRESS IN MATERIALS SCIENCE, 2005, 50 (01) :93-179
[2]   A flexible carbon counter electrode for dye-sensitized solar cells [J].
Chen, Jikun ;
Li, Kexin ;
Luo, Yanhong ;
Guo, Xiaozhi ;
Li, Dongmei ;
Deng, Minghui ;
Huang, Shuqing ;
Meng, Qingbo .
CARBON, 2009, 47 (11) :2704-2708
[3]   EXFOLIATION OF GRAPHITE [J].
CHUNG, DDL .
JOURNAL OF MATERIALS SCIENCE, 1987, 22 (12) :4190-4198
[4]   Flexible graphite for gasketing, adsorption, electromagnetic interference shielding, vibration damping, electrochemical applications, and stress sensing [J].
Chung, DDL .
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2000, 9 (02) :161-163
[5]   Review graphite [J].
Chung, DDL .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (08) :1475-1489
[6]   Electromagnetic interference shielding effectiveness of carbon materials [J].
Chung, DDL .
CARBON, 2001, 39 (02) :279-285
[7]   The electrical resistance of flexible graphite as flowfield plate in proton exchange membrane fuel cells [J].
Fu, Yu ;
Hou, Ming ;
Liang, Dong ;
Yan, Xiqiang ;
Fu, Yunfeng ;
Shao, Zhigang ;
Hou, Zhonjun ;
Ming, Pingwen ;
Yi, Baolian .
CARBON, 2008, 46 (01) :19-23
[8]   Fracture mechanism of flexible graphite sheets [J].
Gu, JL ;
Leng, Y ;
Gao, Y ;
Liu, H ;
Kang, FY ;
Shen, WN .
CARBON, 2002, 40 (12) :2169-2176
[9]   In-Situ Characterization of GRAFCELL® Flexible Graphite Film as Gas Diffusion Layers for PEMFCs [J].
Gurau, Vladimir ;
Zawodzinski, Thomas A. ;
Wayne, Ryan J. .
PROTON EXCHANGE MEMBRANE FUEL CELLS 8, PTS 1 AND 2, 2008, 16 (02) :1651-+
[10]   Lead-acid cells with lightweight, corrosion-protected, flexible-graphite grids [J].
Hariprakash, B. ;
Gaffoor, S. A. .
JOURNAL OF POWER SOURCES, 2007, 173 (01) :565-569