Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

被引：118

作者：

Denny, Jason A. ^{[1
]}

Darensbourg, Marcetta Y. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CHEMICAL REVIEWS | 2015年 / 115卷 / 11期

基金：

美国国家科学基金会;

关键词：

TRANSITION-METAL-COMPLEXES; ACETYL-COA SYNTHASE; NICKEL SUPEROXIDE-DISMUTASE; BRIDGED BINUCLEAR IRON(II); N-HETEROCYCLIC CARBENE; X-RAY-STRUCTURE; ACTIVE-SITE; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; SULFUR LIGANDS;

D O I：

10.1021/cr500659u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to review the use of numerous MN2S2 complexes and their application as metallodithiolate ligands. The investigations focused on contiguous S-N-N-S tetradentate ligands that accommodated square planar binding and present the thiolate sulfurs in the cis-configuration that was conducive for them serving as bidentate S-donor ligands. The study also described bimetallic complexes evolving from MN2S2 metalloligands in combination with a transition metal acceptor bearing diatomic ligands as reporter groups of the electron-donating ability of the MN2S ligands.

引用

页码：5248 / 5273

页数：26

共 195 条

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