Heteropoly complexes containing titanium .2. Synthesis and characterization of titanotungstocobaltates

被引：17
作者：
Chen, YG
Liu, JF
机构：
[1] Department of Chemistry, Northeast Normal University
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 02期
关键词：
D O I：
10.1080/00945719708000149
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New complexes, M(6)H(2)[(CoW11TiO40)-W-II]. xH(2)O (M = K, x = 12; M = (CH3)(4)N, x = 4), [(CH3)(4)N]H-5(2)[(CoW11TiO40)-W-II]. 6H(2)O and [(CH3)(4)N]H-7[(CoW11)-W-II(TiO2)O-39]. 4H(2)O, have been synthesized and characterized by elemental analysis, IR, UV-Vis and ESR spectroscopy and X-ray photoelectronic spectroscopy. The results show that the three anions have Keggin structure. Their redox property was also examined.
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页码：239 / 249
页数：11
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