Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia

被引：188

作者：

Yamaguchi, Kazuya ^{[1
]}

Kobayashi, Hiroaki ^{[1
]}

Oishi, Takamichi ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 02期

关键词：

alcohols; amides; ammonia; heterogeneous catalysis; manganese oxide; OCTAHEDRAL MOLECULAR-SIEVES; GREEN CHEMISTRY; AMINES; OXIDATION; EFFICIENT; NITRILES; DESIGN; WATER;

D O I：

10.1002/anie.201107110

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a manganese oxide based octahedral molecular sieve (OMS-2), a range of primary amides could be synthesized directly from primary alcohols and ammonia (see scheme). The observed catalysis was heterogeneous, and the recovered catalyst could be reused many times without an appreciable loss of its catalytic performance. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：544 / 547

页数：4

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