Self-cleaning transparent superhydrophobic coatings through simple sol-gel processing of fluoroalkylsilane

被引:209
作者
Liu, Shanhu [1 ,2 ]
Liu, Xiaojing [1 ]
Latthe, Sanjay S. [2 ]
Gao, Li [1 ]
An, Seongpil [3 ]
Yoon, Sam S. [3 ]
Liu, Baoshun [4 ]
Xing, Ruimin [1 ,2 ]
机构
[1] Henan Univ, Coll Chem & Chem Engn, Inst Environm & Analyt Sci, Kaifeng 475001, Peoples R China
[2] Tokyo Univ Sci, Res Inst Sci & Technol, Photocatalysis Int Res Ctr, Noda, Chiba 2788510, Japan
[3] Korea Univ, Sch Mech Engn, Seoul 136713, South Korea
[4] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei Province, Peoples R China
基金
中国国家自然科学基金;
关键词
Superhydrophobic; Self-cleaning; Lotus leaf; Plastron layer; Sol-gel process; Dip coating; ALUMINUM-ALLOY SURFACES; ONE-STEP PROCESS; SILICA FILMS; SILANE; LOTUS; NANOPARTICLES; MORPHOLOGY;
D O I
10.1016/j.apsusc.2015.06.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Upon contact with a dusty superhydrophobic surface, moving spherical water drops collect the dust particles and eventually flow off the surface. Herein, we report a very simple one-step approach to fabricate transparent and self-cleaning superhydrophobic coatings via the sol-gel processing of long-chain fluoroalkylsilane. The coating surface exhibited a rough, wrinkled, hill-like morphology similar to the microstructure of the lotus leaf (rough micro-scale papillae), which is promising for superhydrophobicity. The air bags trapped in the rough, hill-like structure allow the water drops to take a round shape with a contact angle of 169 degrees. These round water drops abruptly roll off the coating surface at less than 5 of tilting. No major or minor water-drop pinning was observed during the roll off. The dust-repellent (self-cleaning) property, plastron stability, and durability against water-jet impact were examined on the superhydrophobic coatings. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:897 / 903
页数:7
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