Complexes of copper(II) carboxylates with ammonia. Crystal structure of Cu(O2CC9H19)(2)(NH3)(2)(H2O)

被引:10
作者
Petric, M [1 ]
Leban, I [1 ]
Segedin, P [1 ]
机构
[1] UNIV LJUBLJANA,FAC CHEM & CHEM TECHNOL,LJUBLJANA 61000,SLOVENIA
关键词
D O I
10.1016/0277-5387(96)00135-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Compounds of the composition CuX(2)(NH3)(2)(H2O) (X = heptanoate, octaneate, nonanoate, decanoate or dodecanoate) were prepared, analysed and characterized by vibrational and electron paramagnetic resonance (EPR) spectroscopy and by magnetic susceptibility measurements. The crystal and molecular structure of diammine-aquabis(decanoato)copper(II) was determined by X-ray diffraction. The structure consists of mononuclear units with (4+2) coordination around central copper. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:4277 / 4282
页数:6
相关论文
共 50 条
  • [21] Synthesis and Crystal Structure of a New Dinuclear Copper(II) Polymer: [Cu2(bipy)2(Hbtc)2(H2O)2]·(H2O)1/2
    陈磅宽
    车云霞
    郑吉民
    Chinese Journal of Structural Chemistry, 2006, (12) : 1427 - 1430
  • [22] Synthesis and crystal structure of a new dinuclear copper(II) polymer:: [Cu2(bipy)2(HbtC)2(H2O)2]•(H2O)1/2
    Chen Pang-Kuan
    Che Yun-Xia
    Meng Ji-Min
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (12) : 1427 - 1430
  • [23] Crystal structure of diaquabis(3-hydroxyquinoxaline-2-carboxylato-κ2N1,O)copper(II) dihydrate, Cu(C9H5N2O3)2(H2O)2 • 2H2O
    Xiao, Bo
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (02): : 169 - 170
  • [24] Crystal Structure of the Copper Complex with Cyanuric Acid Cu(C3H2N3O3)2(H2O)2
    Chen Chang-Zhang
    Shao Shi-Bao
    Huang Xiao-Ying
    Gao Dong-Shou
    Lin Zhou-Bin(Fujian Institute of Research on the Structure of Matter
    结构化学, 1995, (Z1) : 356 - 358
  • [25] Vapor-liquid equilibria of NH3 in (NH3+ H2O) and (NH3 + PZ + H2O) system
    Liu, Jinzhao
    Wang, Shujuan
    Hartono, Ardi
    Svendsen, Hallvard F.
    Kim, Inna
    Chen, Changhe
    FLUID PHASE EQUILIBRIA, 2011, 311 : 30 - 35
  • [26] Estimation of coordination bond energies of NH3, H2O and Et2NH ligands in the Ni(II) and Cu(II) complexes
    Ü. Ergun
    O. Atakol
    F. Z. Eriş
    A. Yücel
    E. Düzgün
    Journal of Thermal Analysis and Calorimetry, 2009, 97 : 1007 - 1014
  • [27] Estimation of coordination bond energies of NH3, H2O and Et2NH ligands in the Ni(II) and Cu(II) complexes
    Ergun, Ue.
    Atakol, O.
    Eris, F. Z.
    Yuecel, A.
    Duezguen, E.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 97 (03) : 1007 - 1014
  • [28] Synthesis and structure of a new copper(II) complex Cu(C13H9N3O2Br)2•H2O
    Zhang, XT
    Zhan, XP
    Wu, DM
    Yang, WB
    Lu, CZ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (03) : 280 - 283
  • [29] Crystal Structure and Magnetic Properties of Complex[(dien)Cu(H2O)(μ-im)Co(NH3)4(μ-im)(H2O)Cu(dien)](NO3)5
    傅德刚
    徐兵
    王国雄
    唐雯霞
    郁开北
    周忠远
    Science in China(Series B), 1994, 37 (08) : 906 - 914
  • [30] SYNTHESIS AND STUDY OF COPPER AMMINE HYDROXIDE AND COPPER HYDROXIDE, HYDRATES CU(OH)2NH3, H2O AND CU(OH)2, H2O
    CUDENNEC, Y
    LECERF, A
    RIOU, A
    GERAULT, Y
    EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1990, 27 (03): : 411 - 420