Complexes of copper(II) carboxylates with ammonia. Crystal structure of Cu(O2CC9H19)(2)(NH3)(2)(H2O)

被引：10
|
作者：
Petric, M [1 ]
Leban, I [1 ]
Segedin, P [1 ]
机构：
[1] UNIV LJUBLJANA,FAC CHEM & CHEM TECHNOL,LJUBLJANA 61000,SLOVENIA
来源：
POLYHEDRON | 1996年 / 15卷 / 23期
关键词：
D O I：
10.1016/0277-5387(96)00135-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Compounds of the composition CuX(2)(NH3)(2)(H2O) (X = heptanoate, octaneate, nonanoate, decanoate or dodecanoate) were prepared, analysed and characterized by vibrational and electron paramagnetic resonance (EPR) spectroscopy and by magnetic susceptibility measurements. The crystal and molecular structure of diammine-aquabis(decanoato)copper(II) was determined by X-ray diffraction. The structure consists of mononuclear units with (4+2) coordination around central copper. Copyright (C) 1996 Elsevier Science Ltd
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收藏
页码：4277 / 4282
页数：6
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