Reductive dechlorination of atrazine using sodium-borohydride catalysed by cobalt(II) phthalocyanines

被引：8

作者：

Poonam ^{[1
]}

Kumari, Pratibha ^{[1
]}

Ahmad, Sohail ^{[1
]}

Chauhan, Shive Murat Singh ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Bioorgan Res Lab, Delhi 110007, India

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 52期

关键词：

Metallophthalocyanines; Atrazine; Sodium borohydride; Reductive dechlorination; PHOTOCATALYTIC DEGRADATION; METAL PHTHALOCYANINES; MECHANISM; OXIDATION; VITAMIN-B12; PORPHYRIN; KINETICS; CO;

D O I：

10.1016/j.tetlet.2011.10.080

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of functional metallophthalocyanines have been synthesized to study their role as a catalyst towards the reductive dechlorination of atrazine using sodium borohydride as a mild reducing agent. The cobalt(II) phthalocyanine bearing nitro groups at the peripheral position is the most efficient catalyst with exceptionally high catalytic activity in comparison to other functional cobalt(II) phthalocyanines. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：7083 / 7086

页数：4

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