Photocatalysis using GaN nanowires

被引:195
作者
Jung, Hye Seong [1 ,2 ]
Hong, Young Joon [1 ,2 ]
Li, Yirui [1 ,2 ]
Cho, Jeonghui [1 ,2 ]
Kim, Yong-Jin [1 ,2 ]
Yi, Gyu-Chul [1 ,2 ]
机构
[1] POSTECH, Natl CRI Ctr Semiconductor Nanorods, Dept Mat Sci & Engn, Pohang 790784, Gyeongbuk, South Korea
[2] POSTECH, Sch Environm Sci & Engn, Pohang 790784, Gyeongbuk, South Korea
关键词
gaN; nanowire; photocatalysis;
D O I
10.1021/nn700320y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photocatalytic activity of GaN nanowires was investigated for the use of GaN nanowires as photocatalysts in harsh environments. GaN nanowires with diameters of 20-50 nm and lengths of 4- 6 mu m were prepared by Ni catalyst-assisted metal-organic chemical vapor deposition. Comparisons of GaN nanowires with GaN submicron dot arrays and thin films showed that GaN nanowires exhibit much better photocatalytic activity, resulting from a high surface-to-volume ratio. In addition, GaN nanowires exhibited good ability to photodegrade organic dye at various pHs, even under strong acidity and alkalinity. The photocatalytic activity of GaN nanowires was also compared with that of ZnO and TiO2 nanowires.
引用
收藏
页码:637 / 642
页数:6
相关论文
共 12 条
  • [1] Heteroepitaxial growth of high-quality GaN thin films on Si substrates coated with self-assembled sub-micrometer-sized silica balls
    An, Sung Jin
    Hong, Young Joon
    Yi, Gyu-Chul
    Kim, Yong-Jin
    Lee, Dong Kun
    [J]. ADVANCED MATERIALS, 2006, 18 (21) : 2833 - +
  • [2] Role of nanoparticles in photocatalysis
    Beydoun, D.
    Amal, R.
    Low, G.
    McEvoy, S.
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 1999, 1 (04) : 439 - 458
  • [3] HETEROGENEOUS PHOTOCATALYSIS
    FOX, MA
    DULAY, MT
    [J]. CHEMICAL REVIEWS, 1993, 93 (01) : 341 - 357
  • [4] Fujishima A., 2000, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, V1, P1, DOI [10.1016/S1389-5567(00)00002-2, DOI 10.1016/S1389-5567(00)00002-2]
  • [5] ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS
    HOFFMANN, MR
    MARTIN, ST
    CHOI, WY
    BAHNEMANN, DW
    [J]. CHEMICAL REVIEWS, 1995, 95 (01) : 69 - 96
  • [6] Photocatalytic activity of gallium nitride for producing hydrogen from water under light irradiation
    Kida, T.
    Minami, Y.
    Guan, G.
    Nagano, M.
    Akiyama, M.
    Yoshida, A.
    [J]. JOURNAL OF MATERIALS SCIENCE, 2006, 41 (11) : 3527 - 3534
  • [7] An overview of semiconductor photocatalysis
    Mills, A
    LeHunte, S
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 108 (01) : 1 - 35
  • [8] ZnO nanoneedles grown vertically on Si substrates by non-catalytic vapor-phase epitaxy
    Park, WI
    Yi, GC
    Kim, MY
    Pennycook, SJ
    [J]. ADVANCED MATERIALS, 2002, 14 (24) : 1841 - 1843
  • [9] Large-scale synthesis and characterization of TiO2-based nanostructures on Ti substrates
    Peng, Xinsheng
    Chen, Aicheng
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (10) : 1355 - 1362
  • [10] Transparent TiO2 sol nanocrystallites mediated homogeneous-like photocatalytic reaction and hydrosol recycling process
    Xie, YB
    Yuan, CW
    [J]. JOURNAL OF MATERIALS SCIENCE, 2005, 40 (24) : 6375 - 6383