Catalytic Decarboxylative Reactions: Biomimetic Approaches Inspired by Polyketide Biosynthesis

被引：117
|
作者：
Pan, Yuanhang [1 ]
Tan, Choon-Hong [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
SYNTHESIS-STUTTGART | 2011年 / 13期
关键词：
decarboxylative reactions; organocatalytic reactions; malonic acid half thioester; asymmetric catalysis; enantioselectivity; ENANTIOSELECTIVE DECARBOXYLATION; CLAISEN CONDENSATION; HALF-THIOESTERS; ALDOL REACTIONS; ESTERS; 1,4-ADDITION; DERIVATIVES; ROUTE;
D O I：
10.1055/s-0030-1260607
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This short review summarizes decarboxylative reactions of malonic acid half thio/oxyester mediated by metal complexes and organocatalysts. These biomimetic reactions are inspired by similar reactions catalyzed by polyketide synthase. While they have been known for several decades, this is the first review of these reactions.
引用
收藏
页码：2044 / 2053
页数：10
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