A smart approach to achieve an exceptionally high loading of metal nanoparticles supported by functionalized extended frameworks for efficient catalysis

被引：66

作者：

Gole, Bappaditya ^{[1
]}

Sanyal, Udishnu ^{[1
]}

Mukherjee, Partha Sarathi ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 23期

关键词：

POROUS COORDINATION POLYMERS; ORGANIC FRAMEWORK; GOLD CLUSTERS; ENCAPSULATION; NANOCRYSTALS; SELECTIVITY; DEPOSITION; REDUCTION; OXIDATION; PORES;

D O I：

10.1039/c4cc09228g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The problem associated with metal nanoparticle (NP) agglomeration when trying to achieve a high loading amount has been solved by a new method of functionalization of MOFs' pores with terminal alkyne moieties. The alkynophilicity of the Au3+ ions has been utilized successfully for an exceptionally high loading (similar to 50 wt%) of Au-NPs on supported functionalized MOFs.

引用

收藏

页码：4872 / 4875

页数：4

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