A smart approach to achieve an exceptionally high loading of metal nanoparticles supported by functionalized extended frameworks for efficient catalysis

被引：66
作者：
Gole, Bappaditya [1 ]
Sanyal, Udishnu [1 ]
Mukherjee, Partha Sarathi [1 ]
机构：
[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 23期
关键词：
POROUS COORDINATION POLYMERS; ORGANIC FRAMEWORK; GOLD CLUSTERS; ENCAPSULATION; NANOCRYSTALS; SELECTIVITY; DEPOSITION; REDUCTION; OXIDATION; PORES;
D O I：
10.1039/c4cc09228g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The problem associated with metal nanoparticle (NP) agglomeration when trying to achieve a high loading amount has been solved by a new method of functionalization of MOFs' pores with terminal alkyne moieties. The alkynophilicity of the Au3+ ions has been utilized successfully for an exceptionally high loading (similar to 50 wt%) of Au-NPs on supported functionalized MOFs.
引用
收藏
页码：4872 / 4875
页数：4
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