Investigating Aggregation Using In Situ Electrochemistry and Small-Angle Neutron Scattering

被引：5

作者：

Randle, Rebecca I. ^{[1
]}

Fuentes-Caparros, Ana M. ^{[1
,2
]}

Cavalcanti, Leide P. ^{[3
]}

Schweins, Ralf ^{[4
]}

Adams, Dave J. ^{[1
]}

Draper, Emily R. ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Scotland

[2] Anton Paar Ltd, St Albans AL40LA, England

[3] ISIS Neutron & Muon Source User Off, Sci & Technol Facil Council, Rutherford Appleton Lab, Harwell Oxford, Didcot OX11 0QX, England

[4] Inst Laue Langevin, Large Scale Struct Grp, F-38042 Grenoble 9, France

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2022年

基金：

英国工程与自然科学研究理事会;

关键词：

ELECTROLYTE; HYDROGEL; GELATION; SANS;

D O I：

10.1021/acs.jpcc.2c03210

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using small-angle neutron scattering to investigate the aggregation of self assembling molecules is well established. Some of these molecules are electrochemically useful, for example, in electrochromic devices. Electrochemistry can also be used in some cases to induce aggregation. Here, we describe an approach whereby electrochemistry can be directly carried out on a sample in the neutron beam, allowing us to monitor changes directly in situ. We exemplify with two examples but highlight that there are many other potential opportunities.

引用

收藏

页码：13427 / 13432

页数：6

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