Self-Humidification of a Polymer Electrolyte Membrane Fuel Cell System With Cathodic Exhaust Gas Recirculation

被引:21
作者
Xu, Liangfei [1 ,2 ,3 ]
Fang, Chuan [1 ,3 ]
Hu, Junming [1 ,3 ]
Cheng, Siliang [1 ,3 ]
Li, Jianqiu [1 ,3 ]
Ouyang, Minggao [1 ]
Lehnert, Werner [2 ,4 ]
机构
[1] Tsinghua Univ, Dept Automot Engn, State Key Lab Automot Safety & Energy, Beijing 100084, Peoples R China
[2] Forschungszentrum Julich, Inst Energy & Climate Res, IEK Electrochem Proc Engn 3, D-52425 Julich, Germany
[3] Collaborat Innovat Ctr Elect Vehicles Beijing, Beijing 100081, Peoples R China
[4] Rhein Westfal TH Aachen, Modeling Electrochem Proc Engn, D-52062 Aachen, Germany
基金
中国国家自然科学基金;
关键词
polymer electrolyte membrane fuel cell; humidification; exhaust gas recirculation; balance of plants; water management; ENERGY MANAGEMENT STRATEGY; CITY BUS; EXPERIMENTAL VALIDATION; ELECTRIC VEHICLES; DYNAMIC-MODEL; TEMPERATURE REGULATION; PARAMETER EXTRACTION; WATER DISTRIBUTIONS; PERFORMANCE; SIMULATION;
D O I
10.1115/1.4038628
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Water management is critical for the operation of a polymer electrolyte membrane fuel cell (PEMFC). For the purposes of high power and long working-lifetime of PEMFCs, external humidifiers are always utilized as a necessary part of balance of plants to keep the imported air and fuel wet. However, they have several disadvantages, and it is beneficial to remove them so as to reduce system volume and to enhance the cold-starting capability. In this paper, a self-humidified PEMFC of an active area 250 cm 2 and cell number 320 is proposed and investigated. The imported dry air on the cathode side is mixed with moisty exhaust gas by using a recirculation valve, and the dry hydrogen on the anode side is humidified by back-diffusion water through the membrane. A nonlinear model is set up based on mass transport and energy conservation equations to capture dynamics of gases in the supply and exhaust manifolds, the gas diffusion layers (GDLs), and the membrane. An analysis is conducted to investigate the influences of parameters on dynamic and stable performances. Simulation results show that system performances can be greatly affected by parameters such as air stoichiometry, current density, exhaust gas recirculation (EGR) ratio, and membrane thickness. By accurately controlling the EGR ratio and carefully selecting design and operation parameters, it is probably for a PEMFC without an external humidifier to have similar system efficiency compared to a traditional system.
引用
收藏
页数:18
相关论文
共 71 条
[1]   Studies on ion-exchange membranes .1. Effect of humidity on the conductivity of Nafion(R) [J].
Anantaraman, AV ;
Gardner, CL .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 414 (02) :115-120
[2]  
[Anonymous], 2003, MODELING CONTROL FUE, DOI DOI 10.1590/S1413-81232013000300003
[3]   Leakage effects on the performance characteristics of a regenerative blower for the hydrogen recirculation of a PEM fuel cell [J].
Badami, M. ;
Mura, M. .
ENERGY CONVERSION AND MANAGEMENT, 2012, 55 :20-25
[4]   Theoretical model with experimental validation of a regenerative blower for hydrogen recirculation in a PEM fuel cell system [J].
Badami, M. ;
Mura, M. .
ENERGY CONVERSION AND MANAGEMENT, 2010, 51 (03) :553-560
[5]   Modeling and control of air stream and hydrogen flow with recirculation in a PEM fuel cell system - I. Control-oriented modeling [J].
Bao, Cheng ;
Ouyang, Minggao ;
Yi, Baolian .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (13) :1879-1896
[6]   A MATHEMATICAL-MODEL OF THE SOLID-POLYMER-ELECTROLYTE FUEL-CELL [J].
BERNARDI, DM ;
VERBRUGGE, MW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (09) :2477-2491
[7]   Low stoichiometry operation of a proton exchange membrane fuel cell employing the interdigitated flow field - A modeling study [J].
Berning, T. ;
Kaer, S. K. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (10) :8477-8489
[8]   Water balance simulations of a polymer-electrolyte membrane fuel cell using a two-fluid model [J].
Berning, T. ;
Odgaard, M. ;
Kraer, S. K. .
JOURNAL OF POWER SOURCES, 2011, 196 (15) :6305-6317
[9]   Operating proton exchange membrane fuel cells without external humidification of the reactant gases - Fundamental aspects [J].
Buchi, FN ;
Srinivasan, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (08) :2767-2772
[10]   Validation of a two-phase multidimensional polymer electrolyte membrane fuel cell computational model using current distribution measurements [J].
Carnes, Brian ;
Spernjak, Dusan ;
Luo, Gang ;
Hao, Liang ;
Chen, Ken S. ;
Wang, Chao-Yang ;
Mukundan, Rangachary ;
Borup, Rodney L. .
JOURNAL OF POWER SOURCES, 2013, 236 :126-137