Metal-Metal Interaction and Flexible Motion of Triple-Decker Polypyridyl Platinum(II) and Palladium(II) Complexes

被引：15
作者：
Kajitani, Yuta [2 ]
Tsuge, Kiyoshi [1 ]
Sasaki, Yoichi [3 ]
Kato, Masako [2 ]
机构：
[1] Toyama Univ, Grad Sch Sci & Engn, Dept Chem, Toyama 9308555, Japan
[2] Hokkaido Univ, Fac Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
[3] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 36期
关键词：
fluxionality; metal-metal interactions; N; S ligands; palladium; platinum; PI-PI INTERACTIONS; MOLECULAR PIVOT-HINGE; SUPRAMOLECULAR RECOGNITION; SPECTROSCOPIC PROPERTIES; TERPYRIDINE COMPLEXES; ELECTRONIC SPECTROSCOPY; CYCLOMETALATED LIGANDS; DINUCLEAR PLATINUM(II); PT-PT; BINUCLEAR;
D O I：
10.1002/chem.201201274
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triple-decker polypyridyl platinum(II) and palladium(II) complexes were prepared using an N,S-bridging ligand. In solution, tight stacking structures were observed at low temperatures, whereas flexible motion was observed at room temperature. These dynamic behaviors are reflected in the electronic absorption and NMR spectra of these complexes (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：11196 / 11200
页数：5
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