A novel colorimetric and fluorometric anion sensor based on BODIPY-calix[4]pyrrole conjugate

被引：6
作者：
Iv, Yongjun [1 ,2 ,4 ]
Xu, Jian [1 ,2 ]
Guo, Yong [1 ,2 ]
Shao, Shijun [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem North West Plant Resources, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China
[3] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[4] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2012年 / 72卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
Calix[4]pyrrole; BODIPY; Fluorescence; Colorimetric; Anion sensor; FLUORESCENT CHEMOSENSOR; ENERGY-TRANSFER; BODIPY DYES; BORON; CALIXPYRROLES; RECEPTORS; POLARITY; SOLVENT; DESIGN; ION;
D O I：
10.1007/s10847-011-9946-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel fluorescent anion sensor 1 based on boradiazaindacenes (BODIPY) derivative was synthesized and its absorption and fluorescence properties were investigated in various solvents. 1 exhibited a red shift of absorption spectrum and fluorescence quenching in varying degree in the presence of F-, AcO-, H2PO4 (-) and Cl- due to multiple hydrogen bonding interactions between these anions and calix[4]pyrrole receptor. As an anion sensor in the visible region, 1 displayed the similar selectivity and sensitivity toward anions compared to the parent calix[4]pyrrole. However, 1 can be used as an effective dual responsive optical sensor for F- via chromogenical and fluorogenical signals.
引用
收藏
页码：95 / 101
页数：7
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