A Three-State Surface-Confined Molecular Switch with Multiple Channel Outputs

被引：66
作者：
Simao, Claudia
Mas-Torrent, Marta [1 ]
Casado-Montenegro, Javier
Oton, Francisco
Veciana, Jaume
Rovira, Concepcio
机构：
[1] Inst Ciencia Mat Barcelona ICMAB CSIC, Bellaterra 08193, Spain
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 34期
关键词：
SELF-ASSEMBLED MONOLAYERS; METAL-ION RECOGNITION; TETRATHIAFULVALENE DERIVATIVES; CATION RECOGNITION; OPTICAL-PROPERTIES; ORGANIC METALS; ELECTRODES; FILMS; ELECTROCHEMISTRY; DISULFIDES;
D O I：
10.1021/ja204898u
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A self-assembled monolayer of a tetrathiafulvalene derivative on indium tin oxide is shown to operate as a ternary redox switch in which the magnetic and optical outputs are employed to provide a readout of the state. This surface-confined molecular switch exhibits excellent reversibility and stability and is thus promising for the development of molecular electronics.
引用
收藏
页码：13256 / 13259
页数：4
相关论文
共 42 条
[1]  
[Anonymous], 1994, Organic Conductors Fundamentals and Applications
[2]   Photo- and electro-chromism of diarylethene modified ITO electrodes - towards molecular based read-write-erase information storage [J].
Areephong, Jetsuda ;
Browne, Wesley R. ;
Katsonis, Nathalie ;
Feringa, Ben L. .
CHEMICAL COMMUNICATIONS, 2006, (37) :3930-3932
[3]  
Balzani V., 2008, MOL DEVICES MACHINES, DOI DOI 10.1002/9783527621682
[4]   Introduction: Molecular conductors [J].
Batail, P .
CHEMICAL REVIEWS, 2004, 104 (11) :4887-4890
[5]   Intermolecular interactions in self-assembled monolayers of tetrathiafulvalene derivatives [J].
Blanchard, Pierre-Yves ;
Aleveque, Olivier ;
Boisard, Severine ;
Gautier, Christelle ;
El-Ghayoury, Abdelkrim ;
Le Derf, Franck ;
Breton, Tony ;
Levillain, Eric .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (06) :2118-2120
[6]   Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes [J].
Canevet, David ;
Salle, Marc ;
Zhang, Guanxin ;
Zhang, Deqing ;
Zhu, Daoben .
CHEMICAL COMMUNICATIONS, 2009, (17) :2245-2269
[7]   Self-assembled monolayers of electroactive polychlorotriphenylmethyl radicals on Au(111) [J].
Crivillers, Nuria ;
Mas-Torrent, Marta ;
Vidal-Gancedo, Jose ;
Veciana, Jaume ;
Rovira, Concepcio .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (16) :5499-5506
[8]   Self-assembled monolayers of a multifunctional organic radical [J].
Crivillers, Nuria ;
Mas-Torrent, Marta ;
Perruchas, Sandrine ;
Roques, Nans ;
Vidal-Gancedo, Jose ;
Veciana, Jaume ;
Rovira, Concepcio ;
Basabe-Desmonts, Lourdes ;
Ravoo, Bart Jan ;
Crego-Calama, Mercedes ;
Reinhoudt, David N. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (13) :2215-2219
[9]   Molecular computing - A layer of logic [J].
de Silva, A. Prasanna .
NATURE, 2008, 454 (7203) :417-418
[10]   Light-powered electrical switch based on cargo-lifting azobenzene monolayers [J].
Ferri, Violetta ;
Elbing, Mark ;
Pace, Giuseppina ;
Dickey, Michael D. ;
Zharnikov, Michael ;
Samori, Paolo ;
Mayor, Marcel ;
Rampi, Maria Anita .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3407-3409
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