Growth of thick AlN layers by hydride vapor-phase epitaxy

被引:84
作者
Kumagai, Y [1 ]
Yamane, T [1 ]
Koukitu, A [1 ]
机构
[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Koganei, Tokyo 1848588, Japan
关键词
crystal structure; hydride vapor-phase epitaxy; nitrides; semiconducting aluminum compounds;
D O I
10.1016/j.jcrysgro.2005.03.011
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Growth of AlN on sapphire (0 0 0 1) substrates by hydride vapor-phase epitaxy (HVPE) was investigated using AlCl3 and NH3 as source gases in the temperature range from 950 to 1100 degrees C. It was found that the full-width at half-maximum (FWHM) values of the X-ray diffraction (XRD) rocking curves of the (0 0 0 2) and (1 0 (1) over bar 0) planes of the c-axis oriented AlN layers decreased with increasing growth temperature. An AlN layer showing a mirror-like surface could be grown at 1100 degrees C with a growth rate of 1.7 mu m/h. Growth rate was found to increase with increasing AlCl3 input partial pressure and with decreasing distance (L) between the end of the AlCl3 injection nozzle and the sapphire substrate. The growth rate reached 122 mu m/h with an AlCl3 input partial pressure of 2.0 x 10(-3) atm and L = 25 mm but the crystalline quality became poor when the growth rate rose above 10 mu m/h. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:62 / 67
页数:6
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