Synthesis and crystallographic characterisation of silver complexes with the ligand diferrocenylphenylphosphine

被引：14
作者：
Gimeno, MC
Jones, PG
Laguna, A [1 ]
Sarroca, C
机构：
[1] Univ Zaragoza, ICMA, Dept Quim Inorgan, E-50009 Zaragoza, Spain
[2] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
POLYHEDRON | 1998年 / 17卷 / 21期
关键词：
silver; ferrocene; diferrocenylphenylphosphine;
D O I：
10.1016/S0277-5387(98)00129-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Diferrocenylphosphine (PFc(2)Ph) reacts with Ag(TfO) or [Ag(TfO)(PR3)] (TfO = trifluoromethanesulfonate) to afford the three-coordinate complexes [Ag(TfO)(PFc(2)Ph)(2)] or [Ag(TfO)(PFc(2)Ph)(PR3)] (PR3 = PPh2Me, PPh3), respectively. The complex [Ag(TfO)(PFc(2)Ph)(2)] further reacts with bidentate ligands, such as bis(diphenylthiophosphoryl)methane (dptpm) or S2CNEt2- leading to the cationic, [Ag(PFc(2)Ph)(2)(dptpm)]TfO, or neutral, [Ag(S2CNEt2)(PFc(2)Ph)(2)], four-coordinate complexes. The reaction with 1,10-phenanthroline (phen) gives to the four-coordinate [Ag(TfO)(PFc(2)Ph)(phen)]. (C) 1998 Elsevier Science Ltd. oil rights reserved. (C) 1998 Elsevier Science Ltd. All rights reserved.
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收藏
页码：3681 / 3688
页数：8
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