Organic-inorganic hybrid materials doped with lithium ions

被引：0
|
作者：
Zelazowska, Elzbieta [1 ]
Borczuch-Laczka, Maria [2 ]
Rysiakiewicz-Pasek, Ewa [3 ]
机构：
[1] Inst Glass & Ceram, Cracow Branch, Ul Lipowa 3, PL-30702 Krakow, Poland
[2] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, PL-30059 Krakow, Poland
[3] Wroclaw Univ Technol, Inst Phys, PL-50370 Wroclaw, Poland
来源：
OPTICA APPLICATA | 2008年 / 38卷 / 01期
关键词：
organic-inorganic hybrids; lithium-ion conductivity; sol-gel;
D O I：
暂无
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Organic-inorganic hybrid materials have been synthesized by the sol-gel method, using tetraethyl orthosilicate (TEOS), poly(ethylene oxide) (PEO), net-polyacrylic-inter-net-polysiloxane, butyl acrylate, ethyl acetoacetate, tetrahydrofuran, acetonitrile and LiClO4 precursors and additives. Mass fractions of the organic additions in the gels were of ca 35-40 mass%. The hybrid materials obtained were amorphous, colourless, transparent or translucent, with room temperature ionic conductivities in a range of 10(-4_)10(-3) Omega(-1)cm(-1). The results of scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM/EDX), Fourier transform infrared spectroscopy and Si-29 MAS Nuclear Magnetic Resonance analysis have revealed [SiO4] tetrahedrons polycondensation strongly influenced by organic precursors and chemical bonding between organic and inorganic parts of the gels obtained.
引用
收藏
页码：137 / 146
页数：10
相关论文
共 50 条
  • [11] Hybrid organic-inorganic materials based on organophosphorus derivatives
    Vioux, A
    Le Bideau, J
    Mutin, PH
    Leclercq, D
    NEW ASPECTS IN PHOSPHORUS CHEMISTRY IV, 2004, 232 : 145 - 174
  • [12] Ladder-Like Versus Hexagonal Organic-Inorganic Hybrid Materials in the Extraction of Lead Ions
    El-Nakat, John Hanna
    Al-Hakim, Nancy
    Habib, Sami
    Obeid, Pierre
    Zacca, Marie-Jose
    Gracy, Guillaume
    Clement, Sebastien
    Mehdi, Ahmad
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2014, 24 (03) : 508 - 514
  • [13] Sol-gel-derived organic-inorganic hybrid materials
    Han, Yung-Hoe
    Taylor, Alan
    Mantle, Mick D.
    Knowles, Kevin M.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (03) : 313 - 320
  • [14] Hybrid organic-inorganic membranes
    Cornelius, C
    Hibshman, C
    Marand, E
    SEPARATION AND PURIFICATION TECHNOLOGY, 2001, 25 (1-3) : 181 - 193
  • [15] Synthesis of organic-inorganic hybrid azobenzene materials for the preparation of nanofibers by electrospinning
    Bucko, Aleksandra
    Zielinska, Sonia
    Ortyl, Ewelina
    Larkowska, Maria
    Barille, Regis
    OPTICAL MATERIALS, 2014, 38 : 179 - 187
  • [16] Hybrid organic-inorganic sol-gel materials for micro and nanofabrication
    Brusatin, Giovanna
    Della Giustina, Gioia
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2011, 60 (03) : 299 - 314
  • [17] Organic-inorganic hybrid materials: relations of thermal and mechanical properties with structures
    Wei, Y
    Jin, DL
    Yang, CC
    Kels, MC
    Qiu, KY
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 1998, 6 (2-3): : 91 - 98
  • [18] Organic-inorganic hybrid melting gels
    Klein, Lisa C.
    Jitianu, Andrei
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2010, 55 (01) : 86 - 93
  • [19] Recent Advances in Organic and Organic-Inorganic Hybrid Materials for Piezoelectric Mechanical Energy Harvesting
    Vijayakanth, Thangavel
    Liptrot, David J.
    Gazit, Ehud
    Boomishankar, Ramamoorthy
    Bowen, Chris R.
    ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (17)
  • [20] Organic-inorganic hybrid materials towards passive and active architectures for the next generation of optical networks
    Ferreira, R. A. S.
    Andre, P. S.
    Carlos, L. D.
    OPTICAL MATERIALS, 2010, 32 (11) : 1397 - 1409
12345