Heat-induced magnetic properties changes of Mn3[Fe(CN)6]2•xH2O

被引：7
作者：
Liu, Min [1 ]
Xu, Mingxiang [1 ]
机构：
[1] Southeast Univ, Dept Phys, Nanjing 210096, Jiangsu, Peoples R China
来源：
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 9, NO 1 | 2012年 / 9卷 / 01期
关键词：
annealing temperature; infrared spectroscopy; magnetic properties; PHASE-TRANSITION; PRUSSIAN BLUE; CYANIDE; HEXACYANOMETALLATES(II); SPECTROSCOPY;
D O I：
10.1002/pssc.201084184
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Polycrystalline sample of Mn-3[Fe(CN)(6)](2)center dot xH(2)O was prepared by coprecipitation method. The coprecipitated powder was annealed in vacuum at different temperatures of 80, 100, 130, and 150 degrees C respectively. Changes of magnetic properties with different annealed temperatures were studied by Fourier-transform infrared, X-ray diffraction and magnetization measurements. The positive. value of the Curie-Weiss temperature indicates the existence of a predominant ferromagnetic interaction over the anti-ferromagnetic one in the compounds annealed at 80, 100, and 150 degrees C. The negative value of. in Mn-3[Fe(CN)(6)](2)center dot xH(2)O annealed at 130 degrees C appears to be the coexistence of a strong anti-ferromagnetic and a ferromagnetic interactions in the material. This is due to the existence of a relatively strong anti-ferromagnetic contribution between the neighbouring Mn atoms bridged by the oxygen atom of the water molecule. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：89 / 92
页数：4
相关论文
共 19 条
  • [11] Microstructural changes induced by thermal treatment of cobalt(II) hexacyanoferrate(III) compound
    Ng, CW
    Ding, J
    Gan, LM
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2001, 156 (02) : 400 - 407
  • [12] Structure and magnetic properties of Zn-Fe cyanide
    Ng, CW
    Ding, J
    Gan, LM
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2001, 34 (08) : 1188 - 1192
  • [13] OHKOSHI S, 2000, J PHYS CHEM B, V106, P2423
  • [14] Thermal phase transition of RbMnFe(CN)6 observed by X-ray emission and absorption spectroscopy
    Osawa, H
    Iwazumi, T
    Tokoro, H
    Ohkoshi, S
    Hashimoto, K
    Shoji, H
    Hirai, E
    Nakamura, T
    Nanao, S
    Isozumi, Y
    [J]. SOLID STATE COMMUNICATIONS, 2003, 125 (05) : 237 - 241
  • [15] Electrochemically tunable magnetic phase transition in a high-T-c chromium cyanide thin film
    Sato, O
    Iyoda, T
    Fujishima, A
    Hashimoto, K
    [J]. SCIENCE, 1996, 271 (5245) : 49 - 51
  • [16] Photoinduced magnetization of a cobalt-iron cyanide
    Sato, O
    Iyoda, T
    Fujishima, A
    Hashimoto, K
    [J]. SCIENCE, 1996, 272 (5262) : 704 - 705
  • [17] MAGNETIC EXCHANGE INTERACTIONS IN THE LINEAR-CHAIN CHROMIUM(III) COMPOUNDS CATENA-FLUORO(PHTHALOCYANINATO)CHROMIUM(III) AND CATENA-CYANO(PHTHALOCYANINATO)CHROMIUM(III)
    SCHWARTZ, M
    HATFIELD, WE
    JOESTEN, MD
    HANACK, M
    DATZ, A
    [J]. INORGANIC CHEMISTRY, 1985, 24 (24) : 4198 - 4201
  • [18] Verdaguer M., 1993, C COORD CHEM, V14, P19
  • [19] Photoinduced phase transition of RbMnFe(CN)6 studied by x-ray-absorption fine structure spectroscopy -: art. no. 184111
    Yokoyama, T
    Tokoro, H
    Ohkoshi, S
    Hashimoto, K
    Okamoto, K
    Ohta, T
    [J]. PHYSICAL REVIEW B, 2002, 66 (18): : 1 - 10
12