N′-(Adamantan-2-ylidene)thiophene-2-carbohydrazide

被引：8
作者：
Kadi, Adnan A. [2 ]
Alanzi, Amer M. [2 ]
El-Emam, Ali A. [2 ]
Seik Weng Ng [1 ,3 ]
Tiekink, Edward R. T. [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riyadh 11451, Saudi Arabia
[3] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
ANTIINFLAMMATORY ACTIVITIES; DERIVATIVES;
D O I：
10.1107/S1600536811044758
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title molecule, C15H18N2OS, a small twist is noted, with the dihedral angle between the central carbohydrazone residue (r.m.s. deviation = 0.029 angstrom)and the thiophene ring being 12.47 (10)degrees. The syn arrangement of the amide H and carbonyl O atoms allows for the formation of centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. These are linked in the three-dimensional structure by C-H center dot center dot center dot pi interactions. The thiophene ring is disordered over two co-planar orientations, the major component having a site-occupancy factor of 0.833 (2).
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收藏
页码：O3127 / U2252
页数：12
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