Effect of liquid butadiene rubber on mechanical properties of polyamide 11/polyamide 12 blends

被引:3
作者
Simek, Jan [1 ]
Dockalova, Veronika [1 ]
Hrdlicka, Zdenek [1 ]
Duchacek, Vratislav [1 ]
机构
[1] Prague Inst Chem Technol, Dept Polymers, Tech 5, CR-16628 Prague 6, Czech Republic
关键词
blend; impact strength; liquid polybutadiene; mechanical properties; polyamide; AMORPHOUS POLYAMIDE; MOLECULAR-WEIGHT; IMPACT MODIFIER; NYLON-6; ELASTOMERS; BEHAVIOR; MORPHOLOGY;
D O I
10.1515/polyeng-2014-0161
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyamide 11 (PA 11)/polyamide 12 (PA 12) blends with and without liquid polybutadiene (LB) containing isocyanate end groups (LBD) were prepared in the Brabender plastograph. The rubber was added in order to increase the impact strength of the polyamides. Tensile strength and elongation at the upper yield point and hardness were also measured. Thermal properties were determined by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). Fourier transform infrared (FTIR) spectroscopy was used to determine functional groups of polyamides and to reveal possible reactions between the polyamides and LBD. Intrinsic viscosity, measured by an Ubbelohde viscometer, was used to calculate molar mass. The LB has been found as a useful modifier of impact strength.
引用
收藏
页码:349 / 357
页数:9
相关论文
共 18 条
[1]  
[Anonymous], 2000, PRINCIPLES POLYM CHE, DOI [DOI 10.1007/978-1-4615-4227-8, 10.1007/978-1-4615-4227-8]
[2]   Comparison of fracture behavior of nylon 6 versus an amorphous polyamide toughened with maleated poly(ethylene-1-octene) elastomers [J].
Huang, J. J. ;
Paul, D. R. .
POLYMER, 2006, 47 (10) :3505-3519
[3]   Comparison of the toughening behavior of nylon 6 versus an amorphous polyamide using various maleated elastomers [J].
Huang, JJ ;
Keskkula, H ;
Paul, DR .
POLYMER, 2006, 47 (02) :639-651
[4]   Rubber toughening of an amorphous polyamide by functionalized SEBS copolymers: morphology and Izod impact behavior [J].
Huang, JJ ;
Keskkula, H ;
Paul, DR .
POLYMER, 2004, 45 (12) :4203-4215
[5]   Morphology and mechanical properties of polyamide 12 blends with styrene/ethylene-butylene/styrene rubbers with and without maleation [J].
Jose, S ;
Thomas, S ;
Lievana, E ;
Karger-Kocsis, J .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 95 (06) :1376-1387
[6]   DILUTE-SOLUTIONS OF NYLON-12 .2. RELATIONSHIP BETWEEN INTRINSIC-VISCOSITY AND MOLECULAR-WEIGHT [J].
LANSKA, B ;
BOHDANECKY, M ;
SEBENDA, J ;
TUZAR, Z .
EUROPEAN POLYMER JOURNAL, 1978, 14 (10) :807-810
[7]  
Mehrabzadeh M, 1996, J APPL POLYM SCI, V61, P2305, DOI 10.1002/(SICI)1097-4628(19960926)61:13<2305::AID-APP9>3.3.CO
[8]  
2-M
[9]   Moisture absorption by various Polyamides and their associated dimensional changes [J].
Monson, L. ;
Braunwarth, M. ;
Extrand, C. W. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (01) :355-363
[10]   The role of matrix molecular weight in rubber toughened nylon 6 blends .2. Room temperature Izod impact toughness [J].
Oshinski, AJ ;
Keskkula, H ;
Paul, DR .
POLYMER, 1996, 37 (22) :4909-4918