Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products

被引：2

作者：

Akdag, A ^{[1
]}

Tarhan, O ^{[1
]}

Türker, L ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM | 2001年 / 571卷

关键词：

manganese(III) acetate; oxidation; enones; ketones; AM1; calculations;

D O I：

10.1016/S0166-1280(01)00567-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid was carried out. The products were characterized. The experimental results were compared with the theoretical ones which was based on AM1 (UHF) type semi-empirical calculations. The theoretical results disfavor any mechanism solely based on radical stability involving radicals originating from the reactants. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：201 / 206

页数：6

共 9 条

[1] Butenolide annelation using a manganese(III) oxidation.: A synthesis of 4-arylfuran-2(5H)-ones [J].