Luminescent Chromism of Boron Diketonate Crystals: Distinct Responses to Different Stresses

被引:249
作者
Wang, Lu [1 ]
Wang, Kai [2 ]
Zou, Bo [2 ]
Ye, Kaiqi [1 ]
Zhang, Hongyu [1 ]
Wang, Yue [1 ]
机构
[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
[2] Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
MECHANOCHROMIC LUMINESCENCE; HYDROSTATIC-PRESSURE; CONJUGATED MOLECULE; FLUORESCENCE; AGGREGATION; EMISSION; FORCE; COLOR;
D O I
10.1002/adma.201500589
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An organic crystal adopts a molecular packing that can be readily perturbed by external stresses like tensile forces, isotropic pressure, and anisotropic pressure through mechanical smashing, grinding, and compressing, respectively. As a result, the crystals display mechanoluminescence (ML) in response to different mechanical stimuli. The present study provides a model in which three distinct MLs are combined into one organic material. [GRAPHICS] .
引用
收藏
页码:2918 / +
页数:6
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