Rovibronic spectroscopy of MgCH3(A)over-tilde2E←(X)over-tilde2A1 transition

被引：16

作者：

Salzberg, AP ^{[1
]}

Applegate, BE ^{[1
]}

Miller, TA ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Laser Spect Facil, Columbus, OH 43210 USA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1999年 / 193卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1006/jmsp.1998.7756

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We report the laser excitation and dispersed fluorescence spectra of the (A) over tilde(2)E <-- (X) over tilde(2)A(1) transition of the jet-cooled MgCH3, radical. Improvements to the experiment have allowed the observation of 6(0)(1) and 2(0)(1) vibronic features not previously observed. Analyses of these bands, along with the previously reported 0(0)(0) spectra, yield the rotational constants and values of the Coriolis and the spin-orbit coupling constants for the radical's (A) over tilde(2)E state. We also are able to rather completely characterize a small, dynamic Jahn-Teller effect. The dispersed fluorescence spectrum was analyzed and all observed (X) over tilde(2)A(1) state vibrational features were assigned. (C) 1999 Academic Press.

引用

页码：434 / 441

页数：8

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