Biochemical sensing;
Chemical sensing;
Conjugated polymer;
Conjugated polyelectrolyte;
DNA sensing;
Explosives sensing;
Fluorescence;
Fluorescence resonance energy transfer (FRET);
Metal-ion sensing;
Molecular wire effect;
METAL ION-RECOGNITION;
FUNCTIONALIZED POLYFLUORENE;
SENSITIVE DETECTION;
DNA;
POLYTHIOPHENE;
EXPLOSIVES;
ASSAYS;
FILMS;
CHEMOSENSORS;
COPOLYMERS;
D O I:
10.1016/j.trac.2011.04.017
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
This review deals with the emerging field of fluorescent conjugated polymers for the development of chemical and/or biochemical sensors. As a result of their amplified physical properties due to a "molecular wire effect", these materials offer excellent characteristics to develop different sensing schemes (e.g., employing direct superquenching or relying on development of fluorescence-resonance-energy-transfer formats). The versatility of their synthesis procedures allows us to introduce the desired functional groups to achieve analytically useful interactions with analytes [e.g., from transition-metal ions to explosives, or even, in recent years, relevant biomolecules (e.g., proteins or DNA, where conformational changes play a decisive role in detection)]. (C) 2011 Elsevier Ltd. All rights reserved.