Fluorescent conjugated polymers for chemical and biochemical sensing

被引:102
作者
Alvarez, Adrian [1 ]
Salinas-Castillo, Alfonso [2 ]
Costa-Fernandez, Jose M. [1 ]
Pereiro, Rosario [1 ]
Sanz-Medel, Alfredo [1 ]
机构
[1] Univ Oviedo, Dept Phys & Analyt Chem, E-33006 Oviedo, Spain
[2] Univ Granada, Dept Analyt Chem, Fac Sci, E-18071 Granada, Spain
关键词
Biochemical sensing; Chemical sensing; Conjugated polymer; Conjugated polyelectrolyte; DNA sensing; Explosives sensing; Fluorescence; Fluorescence resonance energy transfer (FRET); Metal-ion sensing; Molecular wire effect; METAL ION-RECOGNITION; FUNCTIONALIZED POLYFLUORENE; SENSITIVE DETECTION; DNA; POLYTHIOPHENE; EXPLOSIVES; ASSAYS; FILMS; CHEMOSENSORS; COPOLYMERS;
D O I
10.1016/j.trac.2011.04.017
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This review deals with the emerging field of fluorescent conjugated polymers for the development of chemical and/or biochemical sensors. As a result of their amplified physical properties due to a "molecular wire effect", these materials offer excellent characteristics to develop different sensing schemes (e.g., employing direct superquenching or relying on development of fluorescence-resonance-energy-transfer formats). The versatility of their synthesis procedures allows us to introduce the desired functional groups to achieve analytically useful interactions with analytes [e.g., from transition-metal ions to explosives, or even, in recent years, relevant biomolecules (e.g., proteins or DNA, where conformational changes play a decisive role in detection)]. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1513 / 1525
页数:13
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