Recent Advances in the Chemistry of Phenalenyl

被引：40

作者：

Uchida, Kazuyuki ^{[1
]}

Kubo, Takashi ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Machikaneyama 1-1, Toyonaka, Osaka 5600043, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2016年 / 74卷 / 11期

关键词：

SIGMA-BOND; STACKING INTERACTIONS; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURES; PI-DIMER; RADICALS; DIMERIZATIONS; SPECTROSCOPY; STATE; HEXAFLUOROBENZENE;

D O I：

10.5059/yukigoseikyokaishi.74.1069

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenalenyl radical is an odd-alternant hydrocarbon radical with a highly symmetric (D-3h) structure. The high stability and amphoteric redox nature of this radical have triggered studies on its chemical reactivity, physical properties, and functionalities. The main problem hindering the use of phenalenyl radicals as the molecular components of functional materials is their propensity to sigma-dimerization. Challenging issue will lie in understanding the self-association character and also in controlling the molecular overlap motif. This article summarizes our studies on the self-association behavior of phenalenyl radicals.

引用

页码：1069 / 1077

页数：9

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