Aromatic Metal-Centered Monocyclic Boron Rings: Co©B8- and Ru©B9-

被引：205

作者：

Romanescu, Constantin ^{[2
]}

Galeev, Timur R. ^{[1
]}

Li, Wei-Li ^{[2
]}

Boldyrev, Alexander I. ^{[1
]}

Wang, Lai-Sheng ^{[2
]}

机构：

[1] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

[2] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 40期

基金：

美国国家科学基金会;

关键词：

aromaticity; boron; cluster compounds; coordination modes; transition metals; PLANAR CARBON; AB-INITIO; CLUSTERS; TRANSITION; CATIONS; COBALT; IRON;

D O I：

10.1002/anie.201104166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perfect symmetry: Photoelectron spectroscopy and theoretical calculations show that the B8 and B9 rings are stabilized by the metal atoms in CoB8- and RuB9-, which possess D8h and D9h symmetry, respectively (see picture). The bonding between the metal atom and the boron ring is described by six delocalized σ electrons and six delocalized π electrons, which result in double aromaticity. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9334 / 9337

页数：4

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