Synthesis and characterisation of complexes of the 2,6-diphenoxyphenyl ligand

被引：0

作者：

Blake, Alexander J. ^{[1
]}

Gower, Alexandra L. ^{[1
]}

Lewis, William ^{[1
]}

Moxey, Graeme J. ^{[1
]}

Reade, Thomas J. ^{[1
]}

Kays, Deborah L. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

Silane; Stannane; Lithium; Aryl; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; LITHIUM; COORDINATION; DERIVATIVES; AGGREGATE; BOND; NMR;

D O I：

10.1016/j.jorganchem.2010.12.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of the 2,6-diphenoxyphenyl ligand has facilitated the stabilisation of lithium, silane and stannane complexes. The ortho-metallation reaction between 1,3-(PhO)(2)C6H4 and (BuLi)-Bu-n yields 2,6-(PhO)(2)C6H3Li (1); the crystallographically characterised dimer [2,6-(PhO)(2)C6H3Li(OEt2)](2) ([1.Et2O](2)) can be obtained by the crystallisation of 1 from diethyl ether. The reaction between 1 and Me3ECl gives rise to the structurally authenticated complexes 2,6-(PhO)(2)C6H3EMe3 [E = Si, 2; E = Sn, 3]. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1787 / 1791

页数：5

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