Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

被引：823

作者：

Proust, Anna ^{[1
]}

Thouvenot, Rene ^{[1
]}

Gouzerh, Pierre ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Inorgan & Mat Mol, CNRS, UMR 7071,FR 2769, F-75252 Paris 05, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 16期

关键词：

D O I：

10.1039/b715502f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalization via covalent grafting of organic functions allows to tune the redox and acid - base properties, and the solubility of polyoxometalates, to enhance their stability and biological activity and to reduce their toxicity, to facilitate their implementation in extended structures and functional devices. We discuss herein the electronic and binding connections, and the various synthesis methodologies. We emphasize on organonitrogen, organosilyl and organophosphonyl derivatives with special attention to synthesis, characterization and potential applications in catalysis and materials science. We also consider the giant molybdenum oxidebased clusters especially the porous capsule- type clusters ( Keplerates) which have high relevance to this context.

引用

页码：1837 / 1852

页数：16

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