Halogen bonding in crystal engineering

被引：560

作者：

Metrangolo, Pierangelo ^{[1
,2
]}

Resnati, Giuseppe ^{[1
,2
]}

Pilati, Tullio ^{[3
]}

Biella, Serena ^{[1
,2
]}

机构：

[1] Politecn Milan, NFMLab, Dept Chem Mat & Chem Engn Giulio Natta, I-20131 Milan, Italy

[2] Politecn Milan, I-22100 Como, Italy

[3] Univ Milan, CNR, Inst Mol Sci & Technol, I-20133 Milan, Italy

来源：

HALOGEN BONDING: FUNDAMENTALS AND APPLICATIONS | 2008年 / 126卷

关键词：

halogen bonding; supramolecular chemistry; crystal engineering; tecton; topology;

D O I：

10.1007/430_2007_060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The term halogen bonding encompasses any non-covalent interaction involving halogens as electrophilic species. High strength and directionality are the remarkable features of halogen bonding that fully justify its use as a primary intermolecular interaction to dictate molecular self-assembly processes. This chapter will outline the use of halogen bonding in crystal engineering and will highlight the obtainment of heteromeric crystal structures with complex topologies. Even though the use of halogen bonding is still in its infancy, the growing interest in the field shown by the crystal engineering community promises major advances in the future.

引用

页码：105 / 136

页数：32

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