Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: the crystal structure of Zn(234-MeO-Ba)2En)I2

被引：5

作者：

Khalaji, A. D. ^{[1
]}

Akerdi, S. Jalali ^{[2
]}

Grivani, G. ^{[2
]}

Stoeckli-Evans, H. ^{[3
]}

Das, D. ^{[4
]}

机构：

[1] Golestan Univ, Dept Chem, Fac Sci, Gorgan, Iran

[2] Damghan Univ, Sch Chem, Damghan, Iran

[3] Univ Neuchatel, Inst Phys, Phys Chem Lab, CH-2000 Neuchatel, Switzerland

[4] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 08期

关键词：

ANIONS;

D O I：

10.1134/S1070328411080045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New Symmetric bidentate Schiff-base ligands N,N'-bis(2,3,4-trimethoxybenzylidene)-1,2-di-aminoethane, (234-MeO-Ba)(2)En, and its corresponding zinc(II) and mercury(II) complexes, Zn((234-MeO-Ba)(2)En)I-2 (I), Hg((234-MeO-Ba)(2)En)Cl-2 (II) have been synthesized and characterized by elemental analyses (CHN), FT-IR and 1H NMR spectroscopy. The thermal behaviors of complexes were study using thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. The crystal structure of I was determined from single-crystal X-ray diffraction. The coordination polyhedron about the zinc(II) center in complex I is best described as a distorted tetrahedron.

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收藏

页码：578 / 584

页数：7

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