Probing the bimetallic RhCo3 cluster preserved on SiO2 after thermal treatment under O-2 by hydroformylation

被引:5
|
作者
Huang, L
Xu, Y
机构
[1] State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023 Dalian
关键词
silica-supported RhCo3(CO)(12); oxygen treatment; hydroformylation;
D O I
10.1007/BF00815283
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
RhCo3(CO)(12)/SiO2, after decarbonylation under atmospheric O-2 at 623 K, exhibits excellent catalytic performances in atmospheric ethylene hydroformylation at 423 K, which is consistent with the corresponding catalysis by the bimetallic cluster catalyst RhCo3/SiO2.
引用
收藏
页码:203 / 206
页数:4
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