Combining Microwave Pretreatment with Iron Oxide Nanoparticles Enhanced Biogas and Hydrogen Yield from Green Algae

被引：66

作者：

Zaidi, Asad A. ^{[1
]}

Feng, Ruizhe ^{[1
]}

Malik, Adil ^{[1
]}

Khan, Sohaib Z. ^{[2
,4
]}

Shi, Yue ^{[1
]}

Bhutta, Asad J. ^{[1
]}

Shah, Ahmer H. ^{[3
]}

机构：

[1] Harbin Engn Univ, Coll Power & Energy Engn, Harbin 150001, Heilongjiang, Peoples R China

[2] Islamic Univ Madinah, Fac Engn, Dept Mech Engn, Medina 42351, Saudi Arabia

[3] Balochistan Univ Informat Technol Engn & Manageme, Dept Text Engn, Quetta 87300, Pakistan

[4] Natl Univ Sci & Technol, PN Engn Coll, Dept Engn Sci, Karachi 75350, Pakistan

来源：

PROCESSES | 2019年 / 7卷 / 01期

关键词：

algae; anaerobic digestion; biogas; biohydrogen; energy assessment; kinetic models; microwave; nanoparticles; pretreatment; WASTE ACTIVATED-SLUDGE; ANAEROBIC-DIGESTION; METHANE PRODUCTION; MICROALGAE BIOMASS; CO; DISINTEGRATION; FERMENTATION; IMPACT;

D O I：

10.3390/pr7010024

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The available energy can be effectively upgraded by adopting smart energy conversion measures. The biodegradability of biomass can be improved by employing pretreatment techniques; however, such methods result in reduced energy efficiency. In this study, microwave (MW) irradiation is used for green algae (Enteromorpha) pretreatment in combination with iron oxide nanoparticles (NPs) which act as a heterogeneous catalyst during anaerobic digestion process for biogas enhancement. Batch-wise anaerobic digestion was carried out. The results showed that MW pretreatment and its combination with Fe3O4 NPs produced highest yields of biogas and hydrogen as compared to the individual ones and control. The biogas amount and hydrogen % v/v achieved by MW pretreatment + Fe3O4 NPs group were 328 mL and 51.5%, respectively. The energy analysis indicated that synergistic application of MW pretreatment with Fe3O4 NPs produced added energy while consuming less input energy than MW pretreatment alone. The kinetic parameters of the reaction were scientifically evaluated by using modified Gompertz and Logistic function model for each experimental case. MW pretreatment + Fe3O4 NPs group improved biogas production potential and maximum biogas production rate.

引用

页数：13

共 44 条

[1] Influence of zero valent iron nanoparticles and magnetic iron oxide nanoparticles on biogas and methane production from anaerobic digestion of manure [J].

Abdelsalam, E. ;

Samer, M. ;

Attia, Y. A. ;

Abdel-Hadi, M. A. ;

Hassan, H. E. ;

Badr, Y. .

ENERGY, 2017, 120 :842-853

[2] Effects of Co and Ni nanoparticles on biogas and methane production from anaerobic digestion of slurry [J].

Abdelsalam, E. ;

Samer, M. ;

Attia, Y. A. ;

Abdel-Hadi, M. A. ;

Hassan, H. E. ;

Badr, Y. .

ENERGY CONVERSION AND MANAGEMENT, 2017, 141 :108-119

[3] Comparison of nanoparticles effects on biogas and methane production from anaerobic digestion of cattle dung slurry [J].

Abdelsalam, E. ;

Samer, M. ;

Attia, Y. A. ;

Abdel-Hadi, M. A. ;

Hassan, H. E. ;

Badr, Y. .

RENEWABLE ENERGY, 2016, 87 :592-598

[4]

Antonio F., 2017, GREEN CHEM SUSTAIN T, P3, DOI [10.1007/978-3-319-45459-7, DOI 10.1007/978-3-319-45459-7]

[5] Influence of microwave pre-treatment on sludge solubilization and pilot scale semi-continuous anaerobic digestion [J].

Appels, Lise ;

Houtmeyers, Sofie ;

Degreve, Jan ;

Van Impe, Jan ;

Dewil, Raf .

BIORESOURCE TECHNOLOGY, 2013, 128 :598-603

[6] Aquatic biomass (algae) as a future feed stock for bio-refineries: A review on cultivation, processing and products [J].

Bharathiraja, B. ;

Chakravarthy, M. ;

Kumar, R. Ranjith ;

Yogendran, D. ;

Yuvaraj, D. ;

Jayamuthunagai, J. ;

Kumar, R. Praveen ;

Palani, S. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 47 :634-653

[7] Programmed Iron Oxide Nanoparticles Disintegration in Anaerobic Digesters Boosts Biogas Production [J].

Casals, Eudald ;

Barrena, Raquel ;

Garcia, Ana ;

Gonzalez, Edgar ;

Delgado, Lucia ;

Busquets-Fite, Marti ;

Font, Xavier ;

Arbiol, Jordi ;

Glatzel, Pieter ;

Kvashnina, Kristina ;

Sanchez, Antoni ;

Puntes, Victor .

SMALL, 2014, 10 (14) :2801-2808

[8] Effects of thermal and mechanical pretreatments of secondary sludge on biogas production under thermophilic conditions [J].

Climent, Mavi ;

Ferrer, Ivet ;

del Mar Baeza, Ma ;

Artola, Adriana ;

Vazquez, Felicitas ;

Font, Xavier .

CHEMICAL ENGINEERING JOURNAL, 2007, 133 (1-3) :335-342

[9] Microalgae digestive pretreatment for increasing biogas production [J].

Cordova, Olivia ;

Santis, Julissa ;

Ruiz-Fillipi, Gonzalo ;

Zuniga, Maria Elvira ;

Fermoso, Fernando G. ;

Chamy, Rolando .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2018, 82 :2806-2813

[10] Physical Pretreatment Methods for Improving Microalgae Anaerobic Biodegradability [J].

Cordova, Olivia ;

Passos, Fabiana ;

Chamy, Rolando .

APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 2018, 185 (01) :114-126

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