Effects of sodium laurylsulfate on crystal structure of calcite formed from mixed solutions

被引:10
作者
Bang, Jun-Hwan [2 ,4 ]
Jang, Young Nam [2 ]
Song, Kyung Sun [2 ]
Jeon, Chi Wan [2 ]
Kim, Wonbaek [1 ]
Lee, Myung Gyu [3 ]
Park, So-Jin [4 ]
机构
[1] Korea Inst Geosci & Mineral Resources KIGAM, Mineral Resource Res Div, Taejon 305350, South Korea
[2] Korea Inst Geosci & Mineral Resources KIGAM, Geol Environm Div, Taejon 305350, South Korea
[3] Univ Sci & Technol Korea, Resources Recycling Engn Dept, Taejon 305333, South Korea
[4] Chungnam Natl Univ, Dept Chem Engn, Taejon 305764, South Korea
关键词
Calcite; Solution route; SLS; CMC; Microreactor; Macroreactor; CARBONATE; CRYSTALLIZATION; GROWTH; ULTRAFILTRATION; MORPHOGENESIS; ORGANIZATION; MEMBRANE; IONS;
D O I
10.1016/j.jcis.2010.12.084
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sodium laurylsulfate (SLS), an anionic surfactant, was used for tailoring calcite via a solution route. SLS was dissolved in calcium and carbonate source solutions at various concentrations and critical micelle concentrations (CMCs). The crystallized particles were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), laser-scattering particle size measurements, and thermogravimetric analysis (TGA). Energy dispersive spectroscopy (EDS) analysis was carried out to measure sulfur profiles on the surface of the particles. SLS tended to produce small calcite particles in the carbonate source solution, whereas this effect was not obvious in the calcium source solution. It is believed that the electrostatic repulsion force in the carbonate source solution contributes to the different particle refining effects of SLS seen in the two solutions. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码:311 / 315
页数:5
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