Plasma characteristics and element analysis of steels from a nuclear power plant based on fiber-optic laser-induced breakdown spectroscopy

The laser-produced plasma and laser-induced breakdown spectroscopy (LIBS) of two steels from a nuclear power plant, including the Z3CN20-09M steel used for the main reactor coolant pipes, and the 16MND5 steel used for nuclear reactor pressure vessels. These were investigated based on a fiber-optic LIBS system. Under the same input laser energy, the laser produced plasma from the Z3CN20-09M steel had a weaker emission intensity compared to the 16MND5 steel, probably due to a greater content of Cr. Thus, plasma from the Z3CN20-09M steel had a larger kinetic energy and induced a faster expansion shockwave in air. Calibrations of the fiber-optic LIBS system by the means of internal standardization, support vector regression and random forest regression were set up. For the Cr element, as a major element in Z3CN20-09M (19.33wt.%), it was determined with the relative error controlled under 3.5%; as a trace element (0.11wt.%) in 16MND5 it was measured with the best root mean-square error of prediction as 0.032wt.%, and the Mn content (1.19-1.51wt.%) in both steels was measured with the relative error around 10%.