Ni3S2 nanosheets array supported on Ni foam: A novel efficient three-dimensional hydrogen-evolving electrocatalyst in both neutral and basic solutions

被引：162
作者：
Tang, Chun [1 ]
Pu, Zonghua [1 ]
Liu, Qian [1 ]
Asiri, Abdullah M. [2 ,3 ]
Luo, Yonglan [1 ]
Sun, Xuping [1 ]
机构：
[1] China West Normal Univ, Sch Chem & Chem Engn, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637002, Sichuan, Peoples R China
[2] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia
[3] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 21589, Saudi Arabia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 14期
关键词：
Nickel sulfide; Nanosheets array; Ni foam; Hydrogen evolution reaction; Three-dimensional electrocatalysts; GENERATING HYDROGEN; EVOLUTION CATHODE; NANOWIRE ARRAYS; TI PLATE; CATALYSTS; ELECTROLYSIS; SURFACE; FILMS;
D O I：
10.1016/j.ijhydene.2015.02.038
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this communication, we demonstrate for the first time that nickel sulfide nanosheets array supported on Ni foam can be used as an inexpensive three-dimensional electrocatalyst toward the hydrogen evolution reaction in both neutral and basic solutions. The Ni3S2/Ni foam served as an inexpensive, highly active and stable electrode material for water electrolysis. It needs overpotentials of 220 and 396 mV to afford current densities of 10 and 100 mA cm(-2) in neutral media and needs overpotentials of 123 and 260 mV to afford current densities of 10 and 100 mA cm(-2) in basic solutions. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：4727 / 4732
页数：6
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