Engineered Three-Electrode Cells for Improving Solid State Batteries

被引:15
作者
Dugas, Romain [1 ,2 ]
Dupraz, Yves [3 ]
Quemin, Elisa [1 ,2 ]
Koc, Tuncay [1 ,2 ]
Tarascon, Jean-Marie [1 ,2 ]
机构
[1] Coll France, Chim Solide & Energie UMR CNRS 8260, Paris, France
[2] FR CNRS 3459, Reseau Sur Stockage Electrochim Energie, Amiens, France
[3] Univ PSL, Coll France, Ctr Interdisciplinary Res Biol CIRB, CNRS,INSERM, Paris, France
基金
欧洲研究理事会;
关键词
Batteries; Batteries Li-ion; Energy Storage; REFERENCE ELECTRODE DESIGNS; ANIONIC REDOX; IMPEDANCE; SETUPS;
D O I
10.1149/1945-7111/ac208d
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A three electrode cell for use with solid electrolytes is presented. The cell provides a stable reference voltage and leads artefact-free impedance spectra while being easily assembled and air-tight. To prove its versatility, several combinations of electrodes and electrolytes were employed, enabling rapid assessment of the main differences between argyrodite vs lithium phosphorous sulphide electrolytes, oxide vs sulphide active materials or Li-In alloy based anode vs Li foil anode. This new cell design offers a simple and efficient way of identifying the proper electrode-electrolyte components for enhancing solid state battery performances.
引用
收藏
页数:9
相关论文
共 29 条
  • [1] Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries
    Assat, Gaurav
    Tarascon, Jean-Marie
    [J]. NATURE ENERGY, 2018, 3 (05): : 373 - 386
  • [2] Three-Electrode Setups for Lithium-Ion Batteries II. Experimental Study of Different Reference Electrode Designs and Their Implications for Half-Cell Impedance Spectra
    Costard, J.
    Ender, M.
    Weiss, M.
    Ivers-Tiffee, E.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (02) : A80 - A87
  • [3] Theoretical examination of reference electrodes for lithium-ion cells
    Dees, Dennis W.
    Jansen, Andrew N.
    Abraham, Daniel P.
    [J]. JOURNAL OF POWER SOURCES, 2007, 174 (02) : 1001 - 1006
  • [4] Three-Electrode Setups for Lithium-Ion Batteries I. Fem-Simulation of Different Reference Electrode Designs and Their Implications for Half-Cell Impedance Spectra
    Ender, M.
    Illig, J.
    Ivers-Tiffee, E.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (02) : A71 - A79
  • [5] Performance of Li4Ti5O12-based reference electrode for the electrochemical analysis of all-solid-state lithium-ion batteries
    Ikezawa, Atsunori
    Fukunishi, Goro
    Okajima, Takeyoshi
    Kitamura, Fusao
    Suzuki, Kota
    Hirayama, Masaaki
    Kanno, Ryoji
    Arai, Hajime
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2020, 116 (116)
  • [6] Janek J, 2016, NAT ENERGY, V1, DOI [10.1038/NENERGY.2016.141, 10.1038/nenergy.2016.141]
  • [7] Ion transport limitations in all-solid-state lithium battery electrodes containing a sulfide-based electrolyte
    Kaiser, N.
    Spannenberger, S.
    Schmitt, M.
    Cronau, M.
    Kato, Y.
    Roling, B.
    [J]. JOURNAL OF POWER SOURCES, 2018, 396 : 175 - 181
  • [8] Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells
    Kasemchainan, Jitti
    Zekoll, Stefanie
    Jolly, Dominic Spencer
    Ning, Ziyang
    Hartley, Gareth O.
    Marrow, James
    Bruce, Peter G.
    [J]. NATURE MATERIALS, 2019, 18 (10) : 1105 - +
  • [9] High-power all-solid-state batteries using sulfide superionic conductors
    Kato, Yuki
    Hori, Satoshi
    Saito, Toshiya
    Suzuki, Kota
    Hirayama, Masaaki
    Mitsui, Akio
    Yonemura, Masao
    Iba, Hideki
    Kanno, Ryoji
    [J]. NATURE ENERGY, 2016, 1
  • [10] The importance of cell geometry for electrochemical impedance spectroscopy in three-electrode lithium ion battery test cells
    Klink, Stefan
    Madej, Edyta
    Ventosa, Edgar
    Lindner, Armin
    Schuhmann, Wolfgang
    La Mantia, Fabio
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2012, 22 : 120 - 123