Near UV-visible light induced cationic photopolymerization reactions: A three component photoinitiating system based on acridinedione/silane/iodonium salt

被引：40

作者：

Tehfe, Mohamad-Ali ^{[1
]}

Lalevee, Jacques ^{[1
]}

Morlet-Savary, Fabrice ^{[1
]}

Blanchard, Nicolas ^{[2
]}

Fries, Cedric ^{[2
]}

Graff, Bernadette ^{[1
]}

Allonas, Xavier ^{[1
]}

Louerat, Frederic ^{[1
]}

Fouassier, Jean Pierre ^{[1
]}

机构：

[1] Univ Haute Alsace, ENSCMu, CNRS, Dept Photochem, F-68093 Mulhouse, France

[2] Univ Haute Alsace, ENSCMu, CNRS, Lab Organ & Bioorgan Chem,UMR 7015, F-68093 Mulhouse, France

来源：

EUROPEAN POLYMER JOURNAL | 2010年 / 46卷 / 11期

关键词：

Acridinediones; Cationic photopolymerization; Silyl radicals; Oxygen inhibition; Laser diode; Xenon lamp; AERATED MEDIA; LASER-DYES; ACRIDINEDIONE DERIVATIVES; ACRIDINE(1,8)DIONE DYES; TRIARYLSULFONIUM SALTS; INITIATING SYSTEMS; POLYMERIZATION; RADICALS; DECAHYDROACRIDINE-1,8-DIONES; DIPHENYLIODONIUM;

D O I：

10.1016/j.eurpolymj.2010.09.014

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Acridinediones (AD) are attractive dyes exhibiting a strong absorption at about 400 nm When used in the presence of a silane and an iodonium salt they efficiently initiate the free radical promoted cationic photopolymerization of an epoxide under air and upon a xenon lamp a laser diode or sunlight exposure The mechanism analyzed by ESR and laser flash photolysis is discussed and opens a new way for the design of such three-component systems (C) 2010 Elsevier Ltd All rights reserved

引用

页码：2138 / 2144

页数：7

共 50 条

[1] [Anonymous], 1995, PHOTOINITIATION PHOT
[2] ARSU N, 1995, MACROMOL REP, P1257
[3] Highly Conjugated Thiophene Derivatives as New Visible Light Sensitive Photoinitiators for Cationic Polymerization
Aydogan, Binnur
Gunbas, Gorkem E.
Durmus, Asuman
Toppare, Levent
Yagci, Yusuf
[J]. MACROMOLECULES, 2010, 43 (01) : 101 - 106
[4] BAUMANN H, 1984, Z CHEM, V24, P18
[5] BELFIELD KD, 2003, ASC S SERIES, V847
[6] A VISIBLE-LIGHT INITIATING SYSTEM FOR FREE-RADICAL PROMOTED CATIONIC POLYMERIZATION
BI, YB
NECKERS, DC
[J]. MACROMOLECULES, 1994, 27 (14) : 3683 - 3693
[7] Crivello J.V., 1993, RING OPENING POLYM, P157
[8] Crivello J V., Photoinitiators for Free Radical Cationic and Anionic Photopolimerization, V2nd
[9] Radical-Promoted Visible Light Photoinitiated Cationic Polymerization of Epoxides
Crivello, James V.
[J]. JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2009, 46 (05): : 474 - 483
[10] A New Visible Light Sensitive Photoinitiator System for the Cationic Polymerization of Epoxides
Crivello, James V.
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (03) : 866 - 875

← 1 2 3 4 5 →