The role of oxygen in the reaction of ferrocene with benzoyl peroxide

被引：5

作者：

Murinov, Yu. I. ^{[1
]}

Grabovskiy, S. A. ^{[1
]}

Kuramshina, A. R. ^{[1
]}

Antipin, A. V. ^{[1
]}

Kabal'nova, N. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organ Chem, Ufa Sci Ctr, Ufa 450054, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

ferrocene; oxidation; peroxides; kinetics; ION DERIVATIVES; OXIDATION; LIGANDS;

D O I：

10.1134/S1070363215010211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Participation of molecular oxygen in the reaction of ferrocene with benzoyl peroxide in various solvents is demonstrated. The stoichiometry of the reaction ferrocene: oxygen is determined at 2: 1. Based on NMR, IR spectroscopy, iodometry, and elemental analysis of the product the formation of [mu-(peroxy-O:O')]-diferrocenium benzoate is suggested.

引用

页码：123 / 125

页数：3

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